| Title |
Electrochromic properties of 4-ethylenedioxythiophene-2-carbaldehyde N,N-diphenylhydrazone |
| Another Title |
4-Etilendioksitiofeno-2-karbaldehido N,N-difenilhidrazono elektrochrominės savybės. |
| Authors |
Lygaitis, Ramūnas ; Keruckas, Jonas ; Grigoriev, Timofei E ; Makhaeva, Elena E ; Gražulevičius, Juozas Vidas |
| Full Text |
|
| Is Part of |
Materials science = Medžiagotyra.. Kaunas : Technologija. 2009, vol. 15, no. 3, p. 240-242.. ISSN 1392-1320. eISSN 2029-7289 |
| Keywords [eng] |
Electrochromic materials ; Cyclic voltammetry ; 3,4-ethylenedioxythiophene ; Hydrazone |
| Abstract [eng] |
Electrochemical and spectroelectrochemical properties of molecular glass 3,4-ethylenedioxythiophene-2-carbaldehyde N,N-diphenylhydrazone are reported. 3,4-ethylenedioxythiophene-2-carbaldehyde N,N-diphenylhydrazone showed glass transition at 37 °C and relatively high thermal stability with the initial decomposition temperature at 219 °C. The amorphous film of the compound showed cathodic and anodic responses with a homogeneous change of color from yellow to blue-green in the anodic region. At 4 V two new absorption bands arise in the absorption spectrum of the compound studied, which are absent at 0 V. One is near 670 nm and the second is at 770 nm. Addition of polymethylmethacrylate and poly(N-vinylcaprolactam) enhances electrochromic properties of the material. |
| Published |
Kaunas : Technologija |
| Type |
Journal article |
| Language |
English |
| Publication date |
2009 |
| CC license |
|
