Title Free-standing composite films based on thiol-ene and PEDOT: PSS layers for optoelectronic applications /
Authors Abakevičienė, Brigita ; Guobienė, Asta ; Jucius, Dalius ; Lazauskas, Algirdas
DOI 10.3390/polym13081299
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Is Part of Polymers.. Basel : MDPI. 2021, vol. 13, iss. 8, art. no. 1299, p. 1-8.. ISSN 2073-4360
Keywords [eng] PETMP-TTT ; PEDOT:PSS ; composite ; layers ; free-standing film ; mechanical properties
Abstract [eng] Free-standing composite films were fabricated by combining the plane parallel layers of thiol-ene based on pentaerythritol tetrakis(3-mercaptopropionate)-1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione (PETMP-TTT) UV curable polymer and poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) conductive polymer. A systematic analysis was performed with the focus on mechanical performance of the free-standing composite films. The PEDOT:PSS/PETMP-TTT composite exhibited higher values of adhesion force compared to the free-standing PETMP-TTT film due to hydrophilic nature of the PEDOT:PSS layer. The composite was found to be highly transparent in the range of 380–800 nm. The Young’s modulus and tensile strength of PETMP-TTT were found to be 3.6 ± 0.4 GPa and 19 ± 3 MPa, while for PEDOT:PSS/PETMP-TTT to be 3.5 ± 0.3 GPa and 20 ± 3 MPa, respectively. The sheet resistance values of the PEDOT:PSS layer in the composite film were found to be highly stable after a number of bending iterations with slight increase in sheet resistance from 108 to 118 ± 2 Ω/□. The resultant PEDOT:PSS/PETMP-TTT composite can be further used in optoelectronic applications.
Published Basel : MDPI
Type Journal article
Language English
Publication date 2021
CC license CC license description