Title Facile synthesis of silver-doped zinc oxide nanostructures as efficient scaffolds for detection of p-nitrophenol /
Authors Thakur, Deepika ; Sharma, Anshu ; Singh Rana, Dharmender ; Thakur, Nagesh ; Singh, Dilbag ; Tamulevicius, Tomas ; Andrulevicius, Mindaugas ; Tamulevicius, Sigitas ; Shukla, Sudheesh K ; Thakur, Sourbh
DOI 10.3390/chemosensors8040108
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Is Part of Chemosensors.. Basel : MDPI. 2020, vol. 8, iss. 4, art. no. 108, p. 1-15.. ISSN 2227-9040
Keywords [eng] Ag-doped ZnO ; solution combustion ; luminescence ; p-nitrophenol sensing
Abstract [eng] In this paper, silver-doped zinc oxide nanoparticles were synthesized by using a solution combustion technique, in which zinc nitrate is used as an oxidizer and tartaric acid as a fuel. The phase composition, morphology and structural properties of the as-synthesized zinc oxide and silver-doped zinc oxide were established by using powdered X-ray diffraction, field emission scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy studies. Due to well-defined morphologies and crystallinity, the pure zinc oxide and silver-doped zinc oxide nanostructures can be used as effcient chemical sensors for the detection of p-nitrophenol (PNP). ZnO was found to show a low value of the limit of detection (LOD), i.e., 2.175 μM/L, for p-nitrophenol sensing; moreover, a sharp decrease in the limit of detection was observed with an increase in the concentration of silver ions, and the LOD value decreased to 0.669 μM/L for 10 mol % silver-doped zinc oxide. It is therefore concluded that Ag-doped ZnO shows a lower limit of detection as compared to pure ZnO for p-nitrophenol sensing.
Published Basel : MDPI
Type Journal article
Language English
Publication date 2020
CC license CC license description