Title Graphene–metal hybrid plasmonic structures: synthesis, multi-spectroscopic characterization, and stable analyte detection
Translation of Title Grafeno–metalo hibridinės plazmoninės struktūros: sintezė, multispektroskopinis vertinimas, ir stabilus analitės aptikimas.
Authors Monshi, Marjan
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Pages 146
Keywords [eng] graphene ; surface-enhanced Raman spectroscopy ; plasmonic nanostructures ; hybrid materials ; signal stability
Abstract [eng] This dissertation investigates graphene–metal hybrid plasmonic structures for improved stability and performance of surface-enhanced Raman spectroscopy (SERS) substrates. The study combines plasma-enhanced chemical vapor deposition (PECVD), nanostructure engineering, and multi-spectroscopic characterization to explore graphene growth on catalytic substrates and the formation of graphitic shell–metal systems. Particular attention is given to the role of graphene as a protective and functional layer, enabling analyte adsorption, suppression of surface degradation, and long-term signal retention. The work demonstrates UV-SERS capability using nickel-encapsulated graphitic shells and shows that graphene-protected silver nanostructures can retain detectable analyte signals over extended periods. The results contribute to the understanding of stability mechanisms and provide design guidelines for durable and application-oriented SERS platforms.
Dissertation Institution Kauno technologijos universitetas.
Type Doctoral thesis
Language English
Publication date 2026