| Title |
XPS investigation of TiO2/ZrO2/SiO2 films modified with Ag/Au nanoparticles |
| Another Title |
Ag/Au nanodalelėmis modifikuotų TiO2/ZrO2/SiO2 dangų RFS tyrimas. |
| Authors |
Andrulevičius, Mindaugas ; Tamulevičius, Sigitas ; Gnatyuk, Yuriy ; Vityuk, Nadija ; Smirnova, Natalia ; Eremenko, Anna |
| Full Text |
|
| Is Part of |
Materials science = Medžiagotyra.. Kaunas : Technologija. 2008, vol. 14, no. 1, p. 8-14.. ISSN 1392-1320. eISSN 2029-7289 |
| Keywords [eng] |
XPS ; TiO2/ZrO2/SiO2 films ; Noble metals nanoparticles |
| Abstract [eng] |
Nanocomposites of inorganic nanoparticles have attracted considerable attention recently. In present work TiO2/ZrO2/SiO2 ternary films have been prepared using low-temperature sol-gel method. Corresponding alkoxides were used as titanium, zirconium and silicon sources and acetylaceton as complexing agent. The films were deposited onto titanium substrates using dip-coating technique. Samples modified with metal nanoparticles were prepared by adding appropriate metal source into the sol. Subsequent thermal treatment of the films led to crystallization of oxide matrix with incorporated metal nanoparticles, which was monitored by the appearance of the surface plasmon band of Au/Ag metal particles in the UV-VIS spectra of the films. Chemical composition of the films was investigated by X-ray photoelectron spectroscopy (XPS). Films of single, double, triple oxides and triple oxides modified with noble metals were investigated. Comparison of peaks positions in single, double and triple systems led to assumption that produced TiO2/ZrO2/SiO2 films are ternary oxides. It was found that the negative shift of the O 1s peak of oxygen bounded to silicon depends mostly on Ti content in the mixed oxides films. Correlation between oxygen O 1s peak shift, optical band gap decrese and catalytical activity of the films was noticed. |
| Published |
Kaunas : Technologija |
| Type |
Journal article |
| Language |
English |
| Publication date |
2008 |
| CC license |
|
