| Title |
Synthesis of mono- and dibromo-derivatives of 1-phenylpyrazol-3-ol / |
| Authors |
Nedzelskytė, Eglė ; Martynaitis, Vytas ; Šačkus, Algirdas ; Eller, Gernot A ; Holzer, Wolfgang |
| DOI |
10.3390/M551 |
| Full Text |
|
| Is Part of |
Molbank.. Basel : MDPI. 2007, vol. 2007, iss. 3, art. no. M551, p. 1-4.. ISSN 1422-8599 |
| Keywords [eng] |
1-phenylpyrazol-3-ol ; bromination ; O-acetylation ; NMR spectroscopy |
| Abstract [eng] |
Dependent on the reaction conditions, 1-phenylpyrazol-3-ol and bromine give either 4-bromo-1-phenylpyrazol-3-ol (2a) or 4-bromo-1-(4-bromophenyl)pyrazol-3-ol (2b). Treatment of 2a or 2b with refluxing acetic anhydride leads to the corresponding O-acetyl derivatives 3a and 3b, respectively. Detailed spectroscopic data (1H NMR, 13C NMR, 15N NMR, MS, IR) for 2b, 3a and 3b are presented. |
| Published |
Basel : MDPI |
| Type |
Journal article |
| Language |
English |
| Publication date |
2007 |
| CC license |
|
