| Title |
Unveiling the multifunctional properties of dicyanoisophorone derivatives: from white OLEDs and picric acid sensing to nonlinear optics |
| Authors |
Kaur, Khushdeep ; Bezvikonnyi, Oleksandr ; Volyniuk, Dmytro ; Liu, Weizhen ; de Coene, Yovan ; Clays, Koen ; Singh, Kamaljit ; Rashid, Ehsan Ullah ; Dabuliene, Asta ; Navozenko, Oleksandr ; Grazulevicius, Juozas V |
| DOI |
10.1039/d5tc04271b |
| Full Text |
|
| Is Part of |
Journal of materials chemistry C.. Cambridge : Royal Society of Chemistry. 2026, vol. 14, iss. 15, p. 6380-6388.. ISSN 2050-7526. eISSN 2050-7534 |
| Abstract [eng] |
Newly designed and synthesized derivatives of dicyanoisophorone and different donors, i.e., phenylcarbazole, fluorene, phenanthrene and dimethylfluorene, are characterized by high thermal stability and exhibit aggregation-induced emission enhancement. White organic light-emitting diodes with the derivative of fluorene and dicyanoisophorone as the emitter, operating via hybridized local and charge transfer states, are characterized by a color rendering index of 82. The emitter is also used for the detection of picric acid with Stern–Volmer constants of 16.2 × 104 and 2.7 × 103 M−1. The structure-dependent nonlinear optical response with βzzz values in the range of 785–1901 × 10−30 esu measured using the hyper-Rayleigh scattering (HRS) technique reflects the multifunctional potential of these materials. |
| Published |
Cambridge : Royal Society of Chemistry |
| Type |
Journal article |
| Language |
English |
| Publication date |
2026 |
| CC license |
|
