| Title |
Influence of Na2SO4 produced from phosphogypsum conversions on the basic properties of building gypsum / |
| Authors |
Vaičiukynienė, Danutė ; Mockienė, Jūratė ; Nizevičienė, Dalia ; Ramanauskas, Ignas |
| DOI |
10.3390/ma18010158 |
| Full Text |
|
| Is Part of |
Materials.. Basel : MDPI. 2025, vol. 18, iss. 1, art. no. 158, p. 1-15.. ISSN 1996-1944 |
| Keywords [eng] |
Na2SO4 additive ; building gypsum ; chemical phosphogypsum conversion |
| Abstract [eng] |
This study comprises two distinct but interrelated parts. The first part involves optimizing the conditions for the conversion of phosphogypsum to a Ca(OH)2 and Na2SO4 solution. The second part focuses on enhancing the mechanical properties of gypsum through the use of a sodium sulphate additive derived from the conversion of phosphogypsum. An ultrasonic disperser was employed to accelerate the reaction between phosphogypsum and a sodium hydroxide solution. The mean dispersion time was found to be 0.2, 0.5, 1.0, and 2.0 min. The resulting product was a solution of calcium hydroxide and sodium sulfate. The impact of varying quantities of Na2SO4 on the compressive strength and density of building gypsum samples was investigated. An increase in the quantity of sodium sulphate from 0.2% to 2% resulted in a notable rise in the density of the building gypsum samples, from 1127 kg/m3 in the reference sample to 1264 kg/m3 in the sample containing 2% sodium sulphate. Therefore, in all instances, the utilization of the Na2SO4 additive in the gypsum samples resulted in elevated compressive strengths (4.8-8.6 MPa) in comparison to the reference sample devoid of this additive (1.6 MPa). |
| Published |
Basel : MDPI |
| Type |
Journal article |
| Language |
English |
| Publication date |
2025 |
| CC license |
|
