| Title |
Multicomponent synthesis of new fluorescent boron complexes derived from 3-hydroxy-1-phenyl-1H-pyrazole-4-carbaldehyde / |
| Authors |
Savickienė, Viktorija ; Bieliauskas, Aurimas ; Belyakov, Sergey ; Arbačiauskienė, Eglė ; Šačkus, Algirdas |
| DOI |
10.3390/molecules29143432 |
| Full Text |
|
| Is Part of |
Molecules.. Basel : MDPI. 2024, vol. 29, iss. 14, art. no. 3432, p. 1-15.. ISSN 1420-3049 |
| Keywords [eng] |
aggregation-induced emission enhancement ; fluorescence ; iminoboronates ; pyrazoles |
| Abstract [eng] |
Novel fluorescent pyrazole-containing boron (III) complexes were synthesized employing a one-pot three-component reaction of 3-hydroxy-1-phenyl-1H-pyrazole-4-carbaldehyde, 2-aminobenzenecarboxylic acids, and boronic acids. The structures of the novel heterocyclic compounds were confirmed using 1H-, 13C-, 15N-, 19F-, and 11B-NMR, IR spectroscopy, HRMS, and single-crystal X-ray diffraction data. The photophysical properties of the obtained iminoboronates were investigated using spectroscopic techniques, such as UV–vis and fluorescence spectroscopies. Compounds display main UV–vis absorption maxima in the blue region, and fluorescence emission maxima are observed in the green region of the visible spectrum. It was revealed that compounds exhibit fluorescence quantum yield up to 4.3% in different solvents and demonstrate an aggregation-induced emission enhancement effect in mixed THF–water solutions. |
| Published |
Basel : MDPI |
| Type |
Journal article |
| Language |
English |
| Publication date |
2024 |
| CC license |
|
