Title Ferrocene derivatives for improving the efficiency and stability of MA‐free perovskite solar cells from the perspective of inhibiting Ion migration and releasing film stress /
Authors Bi, Huan ; Liu, Jiaqi ; Zhang, Zheng ; Wang, Liang ; Kapil, Gaurav ; Wei, Yuyao ; Kumar Baranwal, Ajay ; Razey Sahamir, Shahrir ; Sanehira, Yoshitaka ; Wang, Dandan ; Yang, Yongge ; Kitamura, Takeshi ; Beresneviciute, Raminta ; Grigalevicius, Saulius ; Shen, Qing ; Hayase, Shuzi
DOI 10.1002/advs.202304790
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Is Part of Advanced science.. Hoboken, NJ : Wiley-VCH. 2023, vol. 10, iss. 35, art. no. 2304790, p. 1-8.. ISSN 2198-3844. eISSN 2198-3844
Abstract [eng] Further improvement of the performance and stability of inverted perovskite solar cells (PSCs) is necessary for commercialization. Here, ferrocene derivative dibenzoylferrocene (DBzFe) is used as an additive to enhance the performance and stability of MA‐ and Br‐ free PSCs. The results show that the introduction of DBzFe not only passivates the defects in the film but also inhibits the ion migration in the film. The final device achieves a power conversion efficiency (PCE) of 23.53%, which is one of the highest efficiencies currently based on self‐assembled monolayers (SAMs). Moreover, it maintains more than 96.4% of the original efficiency when running continuously for 400 h at the maximum power point.
Published Hoboken, NJ : Wiley-VCH
Type Journal article
Language English
Publication date 2023
CC license CC license description